tert-Amyl Hydroperoxide

tert-Amyl Hydroperoxide. CAS Number: 3425-61-4. EINECS: 222-321-7.

Main Applications
Polymerization

Product Appearance & Packaging

Product Specifications

Product Nametert-Amyl Hydroperoxide
Chemical Nametert-Amyl Hydroperoxide
CAS Number3425-61-4
EINECS/ELINCS No.222-321-7
Molecular Weight104.1 g/mol
Active Oxygen Content8.76%-8.99%
AppearanceClear liquid
UN ClassificationOrganic peroxide type F; liquid, Division 5.2; UN 3109
Packaging20 kg
Organic peroxide type F; liquid, Division 5.2; UN 3109

Industrial Applications

Initiator (85% active ingredient in water) for (co)polymerization of acrylates and methacrylates.

Half-Life Data

Half-life (t½) data for tert-Amyl Hydroperoxide measured in chlorobenzene:

Half-Life (t½)Temperature
0.1 hr228°C
1 hr190°C
10 hr153°C

Thermal Stability

Organic peroxides are thermally unstable substances which may undergo self-accelerating decomposition. The Self Accelerating Decomposition Temperature (SADT) is the lowest temperature at which self-accelerating decomposition may occur.

80°C
SADT

Recommended Storage

35°C
Maximum Storage Temp (Ts Max.)
-5°C
Minimum Storage Temp (Ts Min.)
3 months
Shelf Life

Note: When stored according to these recommended conditions, tert-Amyl Hydroperoxide will remain within specifications for a period of at least 3 months after delivery.

Major Decomposition Products

In the event of thermal decomposition, tert-Amyl Hydroperoxide produces the following major decomposition products:

Methanetert-Amyl alcoholEthanePropane